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By the Late Bronze Age, Hittite had started losing ground to its close relative Luwian. It appears that in the 13th century BC, Luwian was the most-widely spoken language in the Hittite capital, Hattusa. Hittite is the earliest-attested of the Indo-European languages and is the best-known of the Anatolian languages. In one case, the label is Kanisumnili, “in the of the people of Kaneš”. Although the Hittite Empire had people from many diverse ethnic and linguistic backgrounds, the Hittite language was used in most secular written texts. In spite of various arguments over the appropriateness of the term, Hittite remains the most current term because of convention and the strength of association with the Biblical Hittites. The alternative term Nesite, derived from nesili, never caught on.

The first substantive claim as to the affiliation of Hittite was made by Jørgen Alexander Knudtzon in 1902 in a book devoted to two letters found at El-Amarna, Egypt, between the king of Egypt and a Hittite ruler. Hittite is one of the Anatolian languages and is known from cuneiform tablets and inscriptions that were erected by the Hittite kings. The script formerly known as “Hieroglyphic Hittite” is now termed Hieroglyphic Luwian. Unlike other Indo-European languages, Hittie does not distinguish between masculine and feminine grammatical gender, and it lacks subjunctive and optative moods as well as aspect.

Various hypotheses have been formulated to explain those differences. Some linguists, most notably Edgar H. Proto-Indo-European with the full range of features, but the features became simplified in Hittite. According to Craig Melchert, the current tendency is to suppose that Proto-Indo-European evolved and that the “prehistoric speakers” of Anatolian became isolated “from the rest of the PIE speech community, so as not to share in some common innovations”. Hittite has many loanwords, particularly religious vocabulary from the non-Indo-European Hurrian and Hattic languages. The stages are differentiated on both linguistic and paleographic grounds.

Hittite was written in an adapted form of Peripheral Akkadian cuneiform orthography from Northern Syria. The predominantly-syllabic nature of the script makes it difficult to ascertain the precise phonetic qualities of some of the Hittite sound inventory. The limitations of the syllabic script have been more or less overcome by means of comparative etymology and an examination of Hittite spelling conventions. Accordingly, scholars have surmised that Hittite possessed the following phonemes. Long vowels appear as alternates to their corresponding short vowels when they are so conditioned by the accent. Hittite preserves some very archaic features lost in other Indo-European languages.